Yes, the mill isn't the perfect machine for making round cuts, but there are a lot of other cuts involved that require the mill and the time to chuck up the part in the lathe, setup the tools, and manually turn it isn't worth it in this particular case. I've milled round cones before with great results, with a 1/2" ball endmill I was really surprised in the quality of the taper, after a light bead blasting you'd never know it wasn't a lathe. I just haven't done a hemisphere before, it seems the quality should be the same results as a cone, but with sin and cos introduced. I don't have a motorized rotary table.
I'll let you know the results when i'm done, still working on the code with much help from Stirling, i'm curious too.