Mach 3 runs in two ways - either Absolute Stop, or Constant Velocity.
To get a precise right angle on a cut, then the x axis must cut - to above the line (to allow for tool clearance) then stop. The Y axis must then start. This happens when you jave the machine set to Absolute Stop - see General Configuration - second column.
In Constant Velocity - which is designed to smooth out changes between multiple straight lines, - the computer calculates the acceleration of the next line, and as the last line slows down, to a stop, it feeds in the acceleration of the next - i.e. it never stops - constant velocity.
You can never, however , get rid of the rounding on an inside angle, because of the tool diameter.